Controlled Polymerization of Acetylenic Monomers with Late Transition Metal Catalysts
نویسندگان
چکیده
منابع مشابه
Dissymmetric dinuclear transition metal complexes as dual site catalysts for the polymerization of ethylene
A series of dissymmetric dinuclear complexes were synthesized, as dual site catalysts in ethylene polymerization, by coupling the allylated a-diimine complexes of the metals Ti, Zr, V, Ni and Pd with the ansa-zirconocene complex [C5H4-SiH(Me)-C5H4]ZrCl2 possessing a hydride silane moiety. The different stages of syntheses included the formation of bis(cyclopentadienide)methyl silane which was u...
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Quantitative structure–thermostability relationship was carried out for four series of bis(imino)pyridine iron (cobalt) complexes and α-diimine nickel complexes systems in ethylene oligo/polymerization. Three structural parameters were correlated with thermal stability, including bond order of metal-nitrogen (B), minimum distance (D) between central metal and ortho-carbon atoms on the aryl moie...
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Polyolefins are of vast economic importance, which is reflected by an annual production of more than 70 million tons of polyethylene and polypropylene. While the major portion of these materials is produced with Zieglerand chromium-based catalysts, the older free-radical process that affords low-density polyethylene (LDPE) has maintained its significance.[1] Despite the necessity of working at ...
متن کاملdissymmetric dinuclear transition metal complexes as dual site catalysts for the polymerization of ethylene
a series of dissymmetric dinuclear complexes were synthesized, as dual site catalysts in ethylene polymerization,by coupling the allylated a-diimine complexes of the metals ti, zr, v, ni and pd with the ansa-zirconocenecomplex [c5h4-sih(me)-c5h4]zrcl2 possessing a hydride silane moiety. the different stages of syntheses includedthe formation of bis(cyclopentadienide)methyl silane which was util...
متن کاملGroup 4 metal initiators for the controlled stereoselective polymerization of lactide monomers.
Group 4 metal initiators with a tetradentate bis(phenolato) ligand polymerized meso-lactide efficiently under ring-opening to give syndiotactic polylactide. L-Lactide was converted faster than rac-lactide and meso-lactide.
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ژورنال
عنوان ژورنال: KOBUNSHI RONBUNSHU
سال: 2011
ISSN: 0386-2186,1881-5685
DOI: 10.1295/koron.68.210